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master's thesis
Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima
2014. urn:nbn:hr:181:852192
Jozić, Ružica
Josip Juraj Strossmayer University of Osijek
Department of biology

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Jozić, R. (2014). Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima (Master's thesis). Osijek: Josip Juraj Strossmayer University of Osijek, Department of biology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:181:852192

Jozić, Ružica. "Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of biology, 2014. https://urn.nsk.hr/urn:nbn:hr:181:852192

Jozić, Ružica. "Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima." Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of biology, 2014. https://urn.nsk.hr/urn:nbn:hr:181:852192

Jozić, R. (2014). 'Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima', Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of biology, accessed 14 April 2024, https://urn.nsk.hr/urn:nbn:hr:181:852192

Jozić R. Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima [Master's thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of biology; 2014 [cited 2024 April 14] Available at: https://urn.nsk.hr/urn:nbn:hr:181:852192

R. Jozić, "Priprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima", Master's thesis, Josip Juraj Strossmayer University of Osijek, Department of biology, Osijek, 2014. Available at: https://urn.nsk.hr/urn:nbn:hr:181:852192

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Metadata
TitlePriprema kompleksa Fe2+i Fe3+ s nekim organskim ligandima
Title (english)Preparation of the complex Fe 2 + and Fe 3 + with some organic ligands
AuthorRužica Jozić
MentorBerislav Marković (mentor)
Committee memberIvan Vicković (predsjednik povjerenstva)
Committee memberBerislav Marković (član povjerenstva)
Committee memberIvna Štolfa Čamagajevac (član povjerenstva)
GranterJosip Juraj Strossmayer University of Osijek
Department of biology
Osijek
Defense date and country2014-02-07, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Biology
Abstract
U okviru ovog diplomskog rada pripremani su kompleksni spojevi željeza i nekih organskih liganada. Kao polazni spojevi uzete su neke od soli željeza (željezo (II) sulfat heptrahidrat (Fe(SO)4 x 7H2O) , i željezo (III) nitrat nonohidrat, (Fe(NO3)3 x 9 H2O)) koje su miješane sa solima organskih kiselina (vinskom (C4H6O6), limunskom (C6H8O7), oksalnom (C2H2O4), ftalnom (C8H6O4) i anhidrid maleinskom kiseline (C4H2O3)) i etilendiamintetraocten kiselinom EDTA (C10H16N2O2) od kojih su također pripremljene vodene otopne. Reakcijske smjese pripremljene su tako da su vodene otopine Fe2+ i Fe3+ - iona pomiješane s vodenim otopinama organskim kiselinama i EDTA u različitim omjerima i koncentracijama. Iz otopina u kojima se pojavio produkt u obliku kristala, produkti su izolirani i analizirani IR spektrofotometrijom u svrhu identifikacije i određivanja prisutnosti odgovarajućih kompleksa. Očitavanjem IR spektrova ustanovljeno je da su kompleksi spojevi dobiveni u reakcijama Fe2+ i Fe3+ iona s oksalnom kiselinom i EDTA u svim istraživanim omjerima. Dobiveni kompleksi su analizirani termogravimetrijskom analizom TGA i diferencijalno pretražnom kalorimetrijom DSC kako bih se odredila njihova termalna svojstva. Rezultati svih analiza upućuju na zaključak da su u reakcijama nastali: željezo (II) oksalat; FeC2O4 × 2H2O i željezo (III) EDTA; Na[Fe(EDTA)]× 3H2O.
Abstract (english)
Within this thesis complex compounds of iron and some organic ligands were prepared. As startup compounds were taken some of iron salts (Iron(II) Sulfate Heptahydrate (Fe(SO)4 x 7H2O) and Iron(III) Nitrate Nonahydrate (Fe(NO3)3 x 9 H2O)) that were mixed with aqueous solutions of organic acids (Tartaric (C4H6O6), Citric (C6H8O7), Oxalic (C2H2O4), Phthalic (C8H6O4), Maleic acid anhydride (C4H2O3) and ethylenediaminetetraacetic acid EDTA (C10H16N2O2)). Reaction mixtures were prepared by mixing aqueous solutions of Fe2+ i Fe3+ ions with organic acid solutions in different ratios and concentrations. From solutions in which crystal product has appeared, they were isolated and analyzed using IR spectrophotometry for the identification and determination of present complexes. By assigning of IR spectra, it was concluded that complex compounds were produced in reactions of Fe2+ and Fe3+ ions with Oxalic acid and EDTA in all ratios. These complexes were analyzed using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) to investigate their thermal characteristics. Results of all analyses are indicating towards one conclusion: Iron(II) oxalate dihidrate (FeC2O4 × 2H2O) and Iron(III) EDTA dihidrate (Na[FeEDTA(H2O)]× 2H2O) were synthesized.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:181:852192
Study programmeTitle: Master of Science Graduate University Study Programme in Biology and Chemistry; specializations in: Master Education In Chemistry and Biology
Course: Master Education In Chemistry and Biology
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra edukacije biologije i kemije (magistar/magistra edukacije biologije i kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2017-01-13 10:18:42